Usually halacha treats certain areas as dinei mamonos - financial law, and other areas as issur v'heter - ritual law, and the rules for the two areas are often very different. Pidyon haben is a gray area - do we treat this like terumos and ma'asros, where there is an obligation to separate and distribute a % of one's crop to a kohein as a ritual obligation to make the food edible, or is it purely a financial obligation?
One possible difference is raised by the Minchas Chinuch - one can forgive a financial obligation and remove a debt (mechila), but one cannot remove a ritual obligation by forgiving payment. A kohein has no power to forgive the payment without accepting anything, which would seem to indicate that this is a ritual obligation.
The Tzemach Tzedek discusses a case of a woman who gives birth and does not know whether her father was a kohein or levi (which would remove the obligation of pidyon haben). The halacha is "ain holchin b'mamon achar harov" - we do not follow majority in laws of mamonos. Even though if we follow the majority of people we would assume the father is a yisrael and hence there is a pidyon obligation, the tzemach tzedek rules that we treat this as a financial matter and no obligation exists. The Kuntres haSefeikos (6:5) argues. There is much more to discuss on this issue!
I copied this above from the internet. Where can I find further discussion of this issue in English?
Pamela Tamarkin Reis, Branford, CT
We have a lecture on the subject which is available at http://www.dafyomi.co.il/members/shiurim/_m3u.php?f=bech047-daf
Best wishes,
Kollel Iyun Hadaf